Available Higher Degree by Research (HDR) Scholarships
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Conversion of CO2 into value added products using mechanochemistry
Dr Srikanth MatetiResearch topic
Carbon dioxide (CO2) conversion refers to the process of transforming carbon dioxide gas, which is a major greenhouse gas contributing to climate change, into other useful compounds or products. This process aims to mitigate the environmental impact of CO2 emissions while also creating value-added materials or fuels. There are various methods and technologies developed for carbon dioxide conversion, each with its own advantages and challenges. This project aims to find solutions for this.
Optional Criteria/Skill Requirements
- Background knowledge of Nanomaterials and characterization techniques.
- Chemistry background is added advantage.
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In situ characterisation tools for battery manufacturing processes
Professor Sally McArthurResearch topic
Across the manufacturing processes used to produce all types of batteries there are many points at which the materials processes, assembly and testing steps can introduce physical and chemical defects and ultimately produce materials and devices that are not functional. Traditionally we have taken samples from the production line for testing post production, resulting in delays in the process and product integration or the loss of expensive materials due to equipment errors. This project will explore how different analysis techniques could be integrated into manufacturing tools to monitor process variation and provide quality assurance with a goal of reducing waste and optimising process controls. We are looking for applicants who have an interest in manufacturing processes, chemical and physical analysis techniques and an ability to think about systems integration challenges. The project will aim to produce solutions that can be readily integrated into industry and support Australian and global businesses to develop new cost effective and environmentally sustainable energy solutions.
Optional Criteria/Skill Requirements
- Suitable for an engineering graduate or Chemistry/physics graduate.
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Physical-based battery system modelling
Dr Fangfang ChenResearch topic
Multiscale computational models show growing significance in advancing battery technologies today. Those models are based on physical and chemical equations to link battery physical and electrochemical properties to its behaviour, which accelerates the development of new battery materials, designs and algorithms. This is a fast-growing area with a great space to explore. The current research conducted at IFM Deakin University predominantly embraces atomistic molecular modelling methods based on either quantum mechanics or Newton’s law. Those modelling tools have been used for battery materials design at the nanometre scale and smaller dimensions. However, there is a great gap here in Australia’s research landscape when it comes to the adoption and development of newly emergent physical-based models for the design the battery systems from the micrometre to millimetre scale, which could benefit both battery research and manufacturing.
With the inauguration of the Battery Research Hub 2.0 and the fast development in battery prototyping technologies, our research has generated a generous amount of lab data that could be used as model parameters for physics-based battery system modelling. Different models have been developed in recent years, particularly for advancing lithium-ion battery technology, such as battery lifetime models, porous electrode models, thermal models, degradation models and so on. In this research, we will integrate and deploy pre-existing models in our research and aim to develop new models for future advanced batteries. This work will collaborate with Prof Alejandro A. Franco (The University of Picardy Jules Verne) whose team has unique expertise in physical-based modelling for battery systems (https://www.modeling-electrochemistry.com/research). The work also has a potential opportunity to collaborate with our existing industry partner Calix to develop real industry applications.
Optional Criteria/Skill Requirements
- A science degree in physics, material physics, or physical chemistry.
- Proficiency in mathematics.
- Proficiency in at least one coding skill, such as Python.
- Experience with atomistic-based modeling, like molecular dynamics, is advantageous but not mandatory.
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Design and understanding of superior ionic electrolytes utilising novel cation and anion structures
Professor Jenny PringleResearch topic
The advancement of safer, next generation energy storage devices such as sodium or lithium metal batteries requires expanding the range of suitable ionic electrolytes and deep understanding of how the different chemical structures impact the important thermal, physical and electrochemical properties. It is now well known that the nature of the cations and anions used to make ionic liquid (IL) electrolytes can have a significant impact on their chemical and physical properties. The same is true for organic ionic plastic crystals (OIPCs); these salts are structurally analogous to ILs but they are solid at room temperature and display dynamics that can allow their use as solid state electrolytes. However, the structure-property relationships are arguably even less well understood in OIPCs.
This project will investigate the synthesis, characterisation and application of new IL and OIPC electrolytes by exploring unique combinations of cation and anion structures. This will include use of novel dication structures developed by Prof Lee’s group at Kunsan National University in South Korea. The collaboration between Profs Lee and Pringle has yielded two papers so far (ChemSusChem and PCCP, 2022) and this scholarship will allow the valuable collaboration to continue.
The cations and anions will be chosen specifically to impart excellent electrochemical properties and thus the electrolytes resulting from combinations of these ions are predicted to possess excellent physical and electrochemical properties and enable enhanced device performance. Critical to understanding the IL and OIPC materials will be in-depth characterisation of the materials using solid state and diffusion NMR, led by A/Prof Luke O’Dell.The development of new ionic electrolytes for sodium and lithium batteries requires detailed understanding of both the neat materials and the electrolytes, which are prepared by combination with sodium or lithium salts respectively. This electrolyte characterisation includes understanding of the phase diagram through thermal analysis, the transport properties through techniques such as NMR (solid state and diffusion) and transference number measurements, as well as electrochemical characterisation such as CVs and cell testing. Thus, each new cation and anion combination promises a wealth of new information about how different ion structures influence the properties of both the neat materials and the electrolytes.
This project is well aligned with the IFM’s Energy research theme. It will contribute to our strong reputation in the electrolyte development area and aims to produce electrolytes that would be of interest to our industry partners in storEnergy and BatTRI-Hub and future Linkage projects. It will also help strengthen international collaborations, particularly with Prof Lee, and strengthen our applications for ARC funding through Fellowships, Linkage and Discovery Projects.
Optional Criteria/Skill Requirements
- Synthetic chemistry experience e.g. through a chemistry or materials engineering degree.
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Sustainable Recycling of Aircraft Aluminium Alloys Using Direct Strip Casting
Dr Lu JiangResearch topic
Background:
For decades, aluminium has been the material of choice for those in the aviation and aerospace sectors, owing to its unique blend of lightweight, strength, and ease of work. As the aviation industry gears up for an expected retirement of about 17,000 aircraft by 2030, the urgency for a sustainable and efficient recycling method for aircraft aluminium alloys becomes undeniable. This recycling arena not only offers a lucrative market potential but also boasts a striking reduction in energy consumption and greenhouse gas emissions by approximately 95% compared to the production of virgin aluminium. However, challenges persist. The accumulation of impurity elements in the recycling process often renders many aircraft non-recyclable. Consequently, they are relegated to vast desert graveyards or ‘downcycled’ into lower-value products. This situation embodies both a significant environmental concern and a substantial loss of economic opportunity.Project Aim:
The crux of this PhD research revolves around direct strip casting (DSC) – a revolutionary technique in the aluminium recycling arena. DSC has emerged as a potential remedy for the challenges faced in conventional recycling, as it processes molten aluminium directly into sheets, curbing the formation of detrimental intermetallics. A primary challenge lies in understanding the role of scrap-related impurities in aircraft aluminium alloys produced by direct strip casting. Therefore, the principal goal of this PhD project is to fully understand the effects of scrap-related impurities on the microstructure and mechanical properties of aircraft aluminium alloys produced by direct strip casting.The specific objectives are:
- Impurity Impact on Microstructure: Quantify the effect of impurities on the strip-cast microstructure.
- Precipitation Behaviour Analysis: Understand the effect of impurities on the precipitation behaviour in strip-cast aircraft aluminium alloys.
- Strengthening Mechanisms Elucidation: Understand the strengthening mechanisms involved and develop an analytical strengthening model.
Optional Criteria/Skill Requirements
- Background in materials science and engineering.
- Strong familiarity with metals and alloys and their processing.
- Demonstrated interest in the field of metals and alloys.
Additional qualifications that would be advantageous:
- Exposure and training in electron microscopy.
- Experience with atom probe tomography is a plus.
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Concrete supercapacitor for large-scale structural energy storage
Dr Alastair MacLeodResearch topic
One of the grand challenges of the 21st Century is the generation and storage of electrical energy. Imparting multi-functional capabilities, including supercapacitance (through the introduction of ion conductive and electrically conductive additives), to the most widely produced material on earth, concrete, could provide an alternative medium for large-scale electrical energy storage. The fabrication of a low-cost, mass concrete-based structural supercapacitor material will be revolutionary in the large-scale, robust storage of energy for a wide range of applications, e.g.: off-grid housing, municipal energy storage, remote locations, energy-efficient structures, while maintaining the strength and durability characteristics of conventional concrete.
Prior efforts in this area, including a recent widely-publicised project from the Massachusetts Institute of Technology, have demonstrated electrical storage capability, but have all too often failed in developing a cement-based energy-storing composite with the potential for scaling up to construction scales (agitator truck size, for example), or employing economically feasible additives, electrodes or production processes.
Utilising inexpensive and cement-compatible ionically-conductive additives, such as sodium chloride, in combination with mechanical reinforcing additives (steel, carbon or other fibres, CNTs, GNP) may provide significant enhancements to the ionic conductivity (to above 80 mS/cm2; OPC has an intrinsic ionic conductivity of about 20 mS/cm2), compressive strength, and areal capacitance (above 35 mF/cm2).
Alternative approaches to imparting electrical charge storage capability in cementitious materials have demonstrated rudimentary cement-based batteries, including using MnO2 as the cathode and Zn metal as the anode. There is significant scope for developing more practicable material solutions to attain the same advanced cement composite capability.
The development of an inexpensive, mass concrete-scalable structural electrical storage medium will be revolutionary for the large-scale storage of electrical energy, integrating built infrastructure more closely with renewable energy sources, thus combining the USD 10.5 Trillion global construction industry with the USD 880 Billion renewable energy sector, and providing a range of new applications in low-energy-density electrical energy storage (e.g.: housing battery storage, distributed network storage, etc.).
Optional Criteria/Skill Requirements
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- Materials or civil engineering, preferably some electrochemistry or corrosion experience.
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Machine Learning-assisted Development of Highly Functional Organic Ionic Plastic Crystals for Solid-state Batteries
Dr Hiroyuki UedaResearch topic
Safe, long-lasting, and high-performance rechargeable batteries are required to meet the ever-growing demand for battery-driven worldwide electrification. Current lithium-ion batteries (LIBs) are well-developed energy-storage technologies among commercialised rechargeable batteries that underpin the wireless use of electronic devices. However, as proven by the incessant accidents of LIB fires, the realisation of alternative rechargeable batteries that are inherently safe and have high energy density is of paramount importance to support the prevalent use of rechargeable batteries for electrification. As such, solid-state batteries (SSBs) that use thermally stable solid electrolytes have been studied, but they are facing many obstacles to commercialisation, which is partly due to poor processabilities or low ionic conductivities of solid electrolytes. To address them, this project aims to develop solid electrolytes drastically using a machine-learning (ML) approach, which will predict promising solid electrolytes for SSB applications. The project will synthesise such solid electrolytes and experimentally validate their ground-breaking properties.
The project has three stages: (1) Computational identification, (2) Computational validation, and (3) Experimental validation. Special attention is paid to the development of organic ionic plastic crystals (OIPCs), which are emerging soft solid electrolytes for SSBs, but they have yet to be studied strategically using ML. In Stage 1, the physicochemical properties of neat OIPCs reported in the literature will be collected. Based on this dataset, the correlation among a number of properties, such as OIPC crystalline phase structures, ionic conductivity, electrochemical potential window, thermal behaviour, and ionic interactions will be analysed via ML methods. The trained model then will be used to predict the properties of a few pre-known systems for validation. Then it will be used to predict new OIPCs with potentially promising properties. In Stage 2, the synthetic routes of new OIPCs will be designed, and the new materials will be prepared with experimental characterisations. In Stage 3, these OIPCs will be investigated computationally to give further in-depth understanding at an atomistic level.
This project is well aligned with the IFM’s research themes including “Energy and Energy Transitions” (=Developing SSBs), “Modelling” (=Using ML and molecular dynamics), and “Interfaces” (=Demonstrating practical electrochemical performance of neat OIPCs at electrode–electrolyte interfaces). This project will be undertaken in multiple locations, mainly at the Burwood campus or the Battery Research and Innovation Hub.
The successful outcomes of this project will include a versatile platform for the rapid development of OIPC-based solid electrolytes, which will lead to generating many high-impact journal publications, patents, and conference presentations. The new method will also lay a basis for the future development of ML-assisted models of another type of electrolytes. this project will facilitate new collaborations with other research organisations or faculty, with the potential to attract industrial collaborations. The success of this project will solidify the position of the Battery Research and Innovation Hub as a world-class battery research and development (R&D) facility.
Optional Criteria/Skill Requirements
Skill Requirements:
- Chemistry experience
- Modelling experience (Molecular dynamics simulations)
- The ability to communicate well with colleagues to advance the project
- The ability to analyse data, summarise them as regular reports using software (e.g., Microsoft Word, Excel, and PowerPoint), and report them in an unbiased way
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Development of Bio-PAN based carbon Fibres
Professor Minoo NaebeResearch topic
In recent years, there has been significant research on the chemical conversion of renewable materials such as propionic acid, glutamic acid, and 3-hydroxypropionic acid into acrylonitrile as sustainable alternatives to traditional petrochemical-based routes. The exploring renewable feedstocks for acrylonitrile production presents a promising avenue for sustainable and environmentally friendly carbon fiber manufacturing. The conversion of these renewable chemicals to acrylonitrile offers potential routes that can contribute to reducing the reliance on petrochemical resources and mitigating environmental impacts leading to sustainable carbon fibre production.
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Smart MXene Textiles for Simultaneous Energy Harvesting and Sensing Applications
Dr Jizhen ZhangResearch topic
This research project aims to pioneer the development of smart MXene textiles capable of efficient energy harvesting from body movement and the environment, alongside seamless integration of high-resolution real-time bio-signal sensing capabilities. By incorporating MXenes into textiles, we will address current challenges in energy yield and bio-signal resolution, leading to advancements in wearable technology and sustainable energy solutions.
Objectives:
Energy Harvesting: Develop strategies for efficient energy harvesting using MXene-integrated textiles, exploring piezoelectric, triboelectric, and photovoltaic mechanisms to capture energy from mechanical vibrations and sunlight.Sensing Capability: Integrate sensors onto the MXene textiles for real-time monitoring of environmental parameters, such as temperature, humidity, and strain.
Energy-Sensing Synergy: Investigate how the simultaneous energy harvesting process affects the sensing capabilities of the textile, and optimize the design to achieve a synergistic balance between energy generation and sensing performance.
Optional Criteria/Skill Requirements
Candidates who are passionate about advancing the frontiers of wearable technology, energy harvesting, and sensing are encouraged to apply.
Preferred special skills and expertise:
Materials Science and Engineering: Candidates should have a strong background in materials science and engineering, with a focus on functional materials such as MXenes. Understanding the properties, synthesis methods, and integration techniques of MXenes into textiles is essential.
Energy Harvesting Expertise: Proficiency in energy harvesting mechanisms, including piezoelectric, triboelectric, and photovoltaic processes, will be valuable for optimizing energy conversion efficiency from body movement and ambient sources.
Sensor Development: Experience in sensor design, fabrication, and integration is important to develop high-resolution bio-signal sensing capabilities within the textiles. Knowledge of bioelectronics and signal processing is a plus.
Although special skills and expertise are preferred, the following criteria are deemed critical in the selection process:
Communication Skills: Strong written and verbal communication skills are essential for presenting research findings, collaborating with team members.
Innovation and Creativity: Candidates should be innovative thinkers, capable of proposing novel solutions to challenges in energy harvesting, sensing integration, and wearable technology.
Join us on this journey to redefine textiles and shape the future of energy harvesting and sensing with smart MXene textiles. Your contributions will play a pivotal role in bridging the gap between materials innovation and real-world applications.
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Microplastics - dyes-cocktails for identification methods development
Dr Alessandra SuttiResearch topic
This project aims to develop a simple method (low processing requirements) to stain microplastics in a differential way using fluorescent dye cocktails, to use fluorescence microscopy as an all-in-one tool for microplastics recognition and identification in environmental samples. The project aims to provide faster and more accesible methods to identify and characterise microplastics, especially in the smaller size range (<200 micron), where other methods fail.
Microplastics are emerging anthropogenic pollutants that affect ecosystems in a complex way. For instance, they offer a fertile substrate for some microbial species that are otherwise found in small numbers, causing local biological and chemical imbalance.
While their presence is known to be widespread, the composition of microplastics in the environment appears to vary geographically and temporally and so does their microbiological impact. Knowing which microplastics are where is important to understand their complex bio-impact.
There is still little knowledge on the geo-temporal distribution of microplastics in terms of composition. While the techniques to identify microplastics advance rapidly, the methods used to identify microplastics’ composition still involve extensive processing (strong oxidising conditions, teflon filtration) and take advantage of equipment such as FT-IR microscopes, which are surface-targeting techniques, thus very sensitive to surface contamination. These methods also are limited to the larger microplastics, being often “”blind”” to smaller microplastics (e.g. textile fibres and textile coating debris) which have been demonstrated to be significantly more abundant by number and of greater concern from a toxicity perspective. From an environmental forensics perspective, the current techniques are also very prone to contamination. This project ultimately aims to simplify sample processing and identification to minimise contamination and to increase knowledge gathering.
Fluorescence microscopy has been used widely to highlight microplastics in samples, albeit mostly in a binary manner (as in “”is this plastic? Y/N””), after extensive sample processing. Fluorescence microscopy has also been combined with FT-IR to provide more identification power for microplastics harnessing the solvatochromic effect (fluorescence colour change depending on the plastic). These early results indicate that solvatochromic and diffential dye uptake methods may be suitable for accelerating sample analysis. Many fluorescent dyes are available in the market, but only a few have been tested in the literature.
This project will fill this knowledge gap, by including a range of inexpensive dyes. It will investigate the interactions between fluorescent dyes and their cocktails and microplastics of selected composition. It is hypothesised that the solvatochromic effect and differential dye uptake will provide sufficient differences in the fluorescence signal to facilitate microplastics identification in unknown samples. The project will test the concept and evaluate technique sensitivity and specificity (composition) also in environmental samples. If successful, this project will provide a faster and more accessible way to identify microplastics by composition, analyse material waste streams including textile waste generated in handling and washing textiles and monitor microplastics exposure with the final aim of influencing policy (standards development, etc.). A potential outcome of this project is the identification of plastic-type-specific dye mixtures for use in targeted analysis. Broader impact could be foreseen in accelerating materials identification
Optional Criteria/Skill Requirements
- Chemistry or biochemistry background
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Sustainable Critical Minerals Recovery through Electrochemical Separation
Dr Anthony SomersResearch topic
Critical minerals for the rapidly increasing renewable energy market are in high demand. Most of this demand is currently being met by primary mining production, however, waste streams such as spent batteries and permanent magnets or mining operation tailings are being targeted to supplement supply. The revaluing of such waste streams is seen as essential to both meet demand for these minerals and maximise the sustainability of the industry and has become a key expectation. To economically extract the desired minerals from these streams hydrometallurgy methods are predominantly used, which can be chemically and energy intensive. Production steps often rely on large pH changes, or thermal swings for separation, which can use toxic reagents, be energy intensive and generate secondary waste streams.
Electrochemical separation techniques, such as Capacitive De-Ionisation (CDI), use a potential difference to concentrate a particular species at an electrode and hence separate it from the stream. By reversing the polarisation a concentrated stream is then recovered. Such a step could replace typical recovery methods in hydrometallurgy, which often use the addition of chemicals to a leachate to separate through precipitation and filtration. CDI has proven to be efficient and scalable for applications such as desalination or heavy metal removal from water. It has also been shown that by manipulating an appropriate speciation in the leachate, relatively small potentials can result in high selectivity, thus minimising unwanted side reactions such as water splitting and improving efficiency. Furthermore, the use of onsite renewable energy can be used to directly supply the electrical energy, thus increasing sustainability. The effectiveness of CDI can be enhanced by using ion selective membranes and functionalised electrode coatings, such as poly(vinylferrocene).
This project will investigate the integration of electrochemical and hydrometallurgical separation to improve process sustainability for the recovery of REEs from tailings. Tailings typically have low concentrations of these REEs, particularly with high valent state ions such as REE and thus CDI can be particularly useful. The project will explore the effects of the leaching speciation and electrode functionalisation on the efficiency of electrochemical REE separation. The laboratories at IFM Burwood are well setup for such research, with extensive electrochemistry capabilities and supervisors Somers and Kar have the required skills and experience in electrochemistry, chemistry and characterisation, along with a history of successful student supervision.
A current series of industrial projects to develop an at-scale, serial and multi-stream processing plant for the recovery of critical materials from legacy mine tailings is being undertaken. This industry project is required to be at a relatively high TRL level, thus is based mostly on proven hydrometallurgy techniques. The electrochemical separation project proposed here represents an important opportunity to undertake more fundamental research that could contribute to the project, as for example one modular stream within the process. Successful outcomes would contribute to future funding opportunities, but also make a wider impact on the sustainable and sovereign processing of critical minerals in Australia.
Optional Criteria/Skill Requirements
- A chemistry or materials background is desirable.
Frequently asked questions – Completing a PhD at IFM
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How do I apply?
If you are interested in becoming a student with IFM, please complete our Expression of Interest form.
Specific projects will also be listed in the 2023 project booklet (Coming October 2022).
Want to learn more about your potential supervisors? Check the about us page.
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How long will it take?
At Deakin, students are expected to complete their PhD in three years (full-time study). However, because life happens and research does not always go to plan, some people need a little longer. When you enrol, your maximum candidature date is set at four years (full-time study).
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Can you complete a PhD in less time?
The minimum period of candidature for a PhD is two years. However, it is very uncommon due to the volume and quality of work required to satisfy the requirements of the degree. It takes time to become an expert in your field after all!
If you are looking to undertake a similar program in just two years, consider a Master by Research at IFM (in Engineering or Science) instead. Completing a Master can be a great way to expand your research skills before committing to a PhD. It is also possible to transfer from a Master to a PhD during your candidature.
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How is the degree examined?
The length of a standard PhD thesis (or dissertation) at Deakin is around 80,000 words. At IFM we also require students to complete an oral examination (similar to a defence, or Viva voce in other countries) usually completed over Zoom.
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What is PhD Xtra
Deakin students benefit from an individual learning plan and additional training opportunities as part of the PhD Xtra program.
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Can I get a scholarship?
Australian Government and Deakin funded scholarships are available to help pay for course fees and living costs, and a number of our projects come with externally funded scholarships. Our current project and scholarship opportunities can be found here (filter by level of study to ‘Higher Degrees Research’).
Learn more about Higher Degrees by Research (HDR) at Deakin including entry requirements, here.
Hear from our PhD candidates
Contact
Dr Zoe Smith - Senior HDR Support Coordinator ifm-hdr-admin@deakin.edu.au